Table 2: Listing of 15N (400 MHz) NMR spectral data for 2 inDMSO-d6,
including results obtained by heteronuclear single
quantum coherence shift-correlated (HSQC) and heteronuclear
multiple bond coherence shift-correlated (HMBC).
Position |
Hδ |
Nδ |
Correlation 1H-15N |
(NH) 1 |
7.02
(s) |
93.29 |
H-1,N-1 |
5 |
1.24 (s) |
93.29 |
H1,2,3-5,
N-1 |
6 |
4.39,
4.83 (AB, 14) |
93.29 |
H1,2-6, N-1 |
214.54 |
H1,2-6,
N-7 |
||
299.12 |
H1,2-6,
N-8 |
||
9 |
7.96
(s) |
214.54 |
H3'triazole-9, N-7 |
251.97 |
H3'triazole-9, N-10 |
||
299.12 |
H3'triazole-9, N-8 |
||
11 |
8.20 (s) |
214.54 |
H5'-triazole-11, N-7 |
251.97 |
H5'-triazole-11, N-10 |
Chemical shifts (δ, ppm) and
coupling constants (J, Hz, in parenthesis) obtained of 1D 1H-NMR
spectrum.
15N NMR spectrum of the
compound 2 shows four signals corresponding
to four
nitrogen atoms and
assigning each
signal
to
its
corresponding
nitrogen atom
is carried out
based
mainly
on
the
spectral data
1H-15N
HMBC (Figure 3).