International Journal of Magnetics and Electromagnetism
Volume 7, Issue 1
Coherence Amplification in Off-Diagonal Density Matrix Elements
Dennis J Sorce*
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Dennis J Sorce*
Retired, Center for Magnetic Resonance Research, Minneapolis, USA
Dennis J Sorce, Retired, Center for Magnetic Resonance Research, Minneapolis, MN 55455, USA, Tel: 410-628-2461.
Accepted: August 07, 2021 | Published Online: August 09, 2021
Citation: Sorce DJ (2021) Coherence Amplification in Off-Diagonal Density Matrix Elements. Int J Magnetics Electromagnetism 7:037.
Copyright: © 2021 Sorce DJ. This is an open-access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.
We demonstrate coherence amplification in off-diagonal density matrix elements for a decoherence model for spin ½ particles with applied radio-frequency pulse without relaxation. The method of coherence amplification developed may be of general utility in applications in NMR/MRI.
The manifestation of coherence phenomena is a hallmark of quantum mechanics, differentiating it from classical phenomenon due to the property of superposition in quantum reality due to the linearity of the Schroedinger equation [1-4].
Methods of possible amplification of coherence as quantitated by the absolute value of off-diagonal density matrix elements, may be of use in applications such as quantum computing  and MRI tissue contrast [6,7].
In the Letter, we develop a Possible Methodology of Coherence Enhancement. It is easily implemented and may have value in Venues of NMR/MRI .
Here, is the time-dependent Density Matrix. is a Time Dependent Radio-Frequency Hamiltonian, defined as:
Here, is Boltzmann's Constant.
T is Temperature in Kelvins.
h is Planck's Constant Divided by 2 .
is a Time Constant Characterizing the Decoherence.
If one substitutes Eq (2) into Eq (1), one obtains after "straightforward but tedious algebra":
is the 2 by 2 Identity Matrix.
For Clarity and Completeness, we Explicitly Define the Following Terms:
We adopt the Standard Definition of the Spin-1/2 Cartesian Spin Angular Momentum Operators
Where, Eqs (7b) are the Pauli Matrices .
If one substitutes Eqs (5,6,7a-b) into Eq (4) one finds after manipulations the following set of four first order differential equations in time for the four matrix elements of the defined Density Matrix. We note that the derived system of equations below were numerically verified versus Eq(9) below:
We note that for ease of manipulation and coding, one can rewrite Eqs (1) as:
Using a Numerical Platform such as Mathematica  one can readily Numerically Solve the four Differential equations Eqs (8 a,b,c,d) to obtain the Time-Dependent Matrix Elements .
In Figure 1a, Figure 1b, Figure 1c and Figure 1d we see plotted the dependence in Three-Dimensional Figures of the Four Density Matrix elements which are numerical solutions of Eqs [8a,b,c,d]. We note that the density matrix elements are considered dimensionless [4,6,8,9]. One can readily see there are Maxima at over the domain considered.
In Summary, the Key Results of this effort, is the finding of Maxima for the dependence of Density Matrix element which indicate amplification of the coherences and populations for spin ½ nuclei which are solutions of the system of Eqs [8a,b,c,d] that incorporate Decoherence effects at . The system of Eqs  are to the knowledge of the author unique to the Magnetic Resonance literature.
Such Enhancement may prove to be of utility in Biomedical Applications in NMR/MRI, because the spin angular momenta can be expressed as sums and differences of the spin-1/2 Density Matrix elements which can be shown to exhibit pronounced amplification that are proportional to the Magnetization.