Accepted: April 30, 2019 | Published Online: May 02, 2019

Citation: Joo SH, Arnold RS, Luciano CM, Benedict WW, Collins T, et al. (2019) Physicochemical Characteristics of Nanocomposites under Environmental Exposure Conditions for Space Applications. Int J Nanoparticles Nanotech 5:025.

Copyright: © 2019 Joo SH, et al. This is an open-access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.

Despite well-perceived advancements of nanotechnology for space applications, application of nanotechnology in the aerospace industry has potential challenges in the perspectives of monitoring and accurately measuring types and levels of pollution. Nanomaterials applied for chemical nanosensors should be well characterized and designed to detect contaminant levels different from Earth's. However, a few studies have investigated the transformation and efficacy of aged nanomaterials in sensor development. The present study explored the aging effect of oxygenation, UV irradiation, and heat treatment on selected nanomaterials (i.e., GO, CNTs, ZnO nanowire, TiO₂, and ZnO) in the perspective of sensing performance to detect trace contaminants.

Further, GO-CNT nanocomposite thin films deposited on electrode chips were exposed to the CO₂ gas contaminant, and their electrical resistance was measured. Results indicate significant changes in physicochemical properties (particle size, zeta potential, and absorbance) of the model nanomaterials under oxygenation and UV irradiation, which was further investigated on their electric resistance upon exposure to gaseous contaminants. The assessment of changes to the CO₂-sensing ability of carbon-nanotube or graphene-oxide hybrid thin films suggests decreasing sensitivity under both UV irradiation and oxygenation.

Keywords

Aged nanoparticles, Graphene oxide, Multi-walled carbon nanotube, Gas detection, Space applications

Introduction

Several nanomaterials (NMs) including graphene, carbon nanotubes (CNTs), metal-oxide nanowires (NWs) have recently emerged as intriguing points of research in multidisciplinary fields, since these NMs exhibit enhanced structural, electrical, and optical properties [1-9]. Thus, they may serve as promising sources of innovation in space applications. Examples of such applications include launching equipment into space with desirably lightweight materials (high strength-to-weight ratio), in which nanotechnology plays a key role in the structure that incorporates various devices (e.g., sensors, actuators, electronic and photonic devices) [1-3,10]. Among these devices, particular attention is given to gas sensors, because of their crucial role in managing the hazardous risks of gas accumulation during space missions (e.g., CO, CO₂, methane, NO_x, and SO₂) [11,12]. Development of sensitive, reliable, and lightweight gas sensors (i.e., reducing dependent weight and increasing the structural strength of such devices) for a spacecraft is imperative to ensure accurate monitoring and safer space environments [13,14].

Among NMs applied in gas sensors, graphene oxide (GO) and CNTs exhibit high selectivity and sensitivity, along with their lightweight property, when interacting with gas molecules [1,2,9,10,15,16]. Five model NMs chosen in the present study include GO, ZnO NW, ZnO, TiO₂, and CNTs; these NMs were chosen based on several properties, which include but are not limited to high sensitivity in gas detection (i.e., graphene sensors) [2,9,17], increasing electrical conductance (i.e., GO) and sensing properties at room temperature [2,16], superior operation at room temperature (i.e., CNTs), and increased interaction with gas molecules due to high specific surface area of CNTs [1,10]. Hybrid gas sensors, which are synthesized by incorporating CNTs into metal oxide gas sensors, have been found to have improved gas-sensing capability, due to the improved surface-to-volume ratio that CNTs offer [18].

Zinc oxide, which has promising optical properties, has a wide range of applications (e.g., gas sensing, UV detection, and solar cells) in its nanowire form [19,20]. Additionally, ZnO as a gas sensor has revealed accurate monitoring and rapid response in detecting reactive gases due to its selectivity and sensitivity [21,22]. The versatility of ZnO, which can be manipulated under different environments as a means of gas sensing, enables it to take various forms of nanowires, nanosheets, nanowalls [23,24]. Similarly, the ZnO NW sensor has been found to have great capacity for space applications due to its rapid response to UV radiation and hydrogen gas [19], and resistance of ZnO NWs higher than usual was shown when these were exposed to oxygen [25]. TiO₂ has shown promise in gas applications because of its unique photovoltaic and photocatalytic properties [26,27], and it has the surface composition with unique binding sites, enabling wide selectivity when employed as a gas sensor [28,29]. Further, TiO₂ offers supporting functions for various nanostructures and enhances sensing capacity of hybrid nanosensors [30].

Despite the crucial role of nanotechnology in space devices, the long-term viability of commonly used NMs has not been thoroughly examined, and no study is found regarding the aging effect (long-term viability) of the selected NMs (i.e., CNTs, ZnO, TiO₂, GO, and ZnO nanowires) on sensitivity and selectivity under environmental conditions to detect trace levels of contaminants. The novelty of the present study lies in addressing potential issues regarding aged/transformed NMs and their sensitivity in detecting the levels of contaminants in space. In the study, environmental conditions such as oxygenation, UV irradiation, and heat treatment were chosen to examine the aging effect of the model nanomaterials (CNTs, ZnO, TiO₂, GO, and ZnO nanowires) on sensitivity, and such effect from exposure was studied through monitoring particle size, zeta potential, and absorbance and conducting qualitative analysis of NMs through scanning electronic microscopy (SEM) and transmission electron microscopy (TEM), as well as a CO₂-sensing ability study of CNT/GO hybrid thin films to examine the long-term viability of a CNT-GO sensor.

The overall goal of the present study is to assess the efficacy of the selected NMs when those are exposed to environmental conditions different from Earth's and characterize versatile NMs for their appropriateness in space products. Two hypotheses driven on this research include a) NMs may affect the strength, feasibility, longevity, effectiveness, and even accuracy in measuring/monitoring contaminants of space devices and b) A change in the resistance (ohms) of the thin films (i.e., GO-CNT) after exposure to CO₂ may depend on different environmental conditions in space. Specific objectives include 1) Examining fabrication and characterizing selected single or hybrid NMs and 2) Assessing versatile NMs for their appropriateness in space products.

Materials and Methods

Materials and equipment

The nanomaterials used were multi-walled carbon nanotubes (Sigma-Aldrich Chemistry, St. Louis, MO), single-layered graphene oxide (Advanced Chemical Supplier, Pasadena, CA), zinc-oxide nanopowder (< 50 nm particle size) (Sigma-Aldrich Chemistry, St. Louis, MO), a zinc-oxide nanowire (diameter × length = 50 nm × 300 nm) (Sigma-Aldrich Chemistry, St. Louis, MO), and titanium(IV) oxide nanopowder (< 25 nm particle size) (Sigma-Aldrich Chemistry, St. Louis, MO). The equipment employed include an Adventurer SL Scale (Ohaus, Parsippany, NJ); VWR Stir Plates (VWR, Radnor, PA); a 100 W, 240 V short-wavelength ultraviolet (UVC) lamp; a Precision Hot Water Bath (Thermo Fisher Scientific, Waltham, MA); a pH Probe (Thermo Fisher Scientific, Waltham, MA); a Malvern Zetasizer (Malvern Instruments, Malvern, United Kingdom); a Branson 1510 Sonicator Bath (Branson, Danbury, CT); a Shimadzu UV-1280 Spectrophotometer (Shimadzu Corp, Kyoto, Japan); and a VWR Mini Vortexer (VWR, Radnor, PA).

Analytical procedures of samples

A total volume of 50 mgL^-1 was prepared from deionized water (100 mL) for each of the five nanoparticle compounds studied: graphene oxide (GO), carbon nanotube (CNT), TiO₂, ZnO, and a ZnO nanowire. Four identical suspensions (ZnO, TiO₂, ZnO NW, and GO), which were exposed to the three experimental conditions (heat, oxygen, and UV), and control samples were analyzed for their physicochemical properties and electric resistance. All samples exposed to environmental conditions (oxygenation, UV irradiation, and heat) were subject to 28 cumulative hours per week and during exposure periods, the experimental apparatus was contained in a low-light environment; such a setup was important to restrict extraneous light interference.

The application of exposure conditions is described as follows. Oxygen exposure conditions were achieved by exposing each of the four distinct nanoparticle suspensions to flowing air at a flow rate of 1.021 × 10^-4 m³s^-1. Heat exposure conditions were achieved by exposing suspensions to a water bath at 50 ℃. Ultraviolet exposure conditions were achieved by UV illumination of nanomaterial suspensions using a short-wavelength ultraviolet (UVC) lamp at a voltage of 240 V and a 100 W power. During illumination, the experimental apparatus was enclosed in an aluminum foil to apply UV light and obstruct peripheral light's entry, and the suspensions were held in 'KIMAX' flasks made of borosilicate glass.

To maintain uniformity in the nanomaterial suspensions during exposure, all suspensions were continually stirred while undergoing experimental conditions (except for heat conditions, since the samples were submerged in a water bath). The triplicate set of nanoparticle suspensions was employed as a control group. This set of suspensions remained in a dark, enclosed environment, and non-control group suspensions were also kept in this environment when not undergoing specific exposure conditions.

Analysis of physicochemical properties

Nanoparticle suspensions were exposed for 14 days (over accumulative 56 hours), and triplicate measurements were taken during each run. Particle size and zeta potential were measured using a Malvern Zetasizer from 1 mL aliquots of each suspension. A Thermo Scientific pH probe was utilized to obtain pH measurements from 2 mL aliquots of each suspension, and a Shimadzu UV-1280 Spectrophotometer was used to obtain absorbance measurements from those aliquots. For SEM preparation, each particulate sample was placed on an aluminum stub that was covered with a carbon adhesive tab, coated with a 20 nm thin Pd coating in a Cressington Sputter Coater, placed in an FEI XL-30 Field Emission Scanning Electron Microscope, and imaged at several magnifications. Afterwards, micrographs were saved digitally. As for the TEM analysis, each sample was diluted, and a drop of the solution was placed on a formvar/carbon-coated 20 mesh copper grid and subjected to air drying. Afterwards, the samples were imaged at several magnifications, and a Gatan camera fitted to a Philips CM-10 TEM was used for imaging at the TEM Core Lab at the University of Miami Miller School of Medicine.

Analysis of electrical resistance of GO-CNT nanocomposite thin films

Nanocomposite thin (GO-CNT) films were deposited on an electrode chip in a vacuum cleanroom. The substrate on the electrode chip was made of fresh and aged samples along with exposure conditions (e.g., aged GO-aged CNT, UV-exposed GO-UV-exposed CNT, and oxygenated GO-oxygenated CNT). The electrode chips consisted of micro-fabricated electrodes on the surface of a single-crystal silicon wafer coated with silicon dioxide, diced 1 by 1 cm². Before starting the deposition process, the chips were placed inside of a 50 mL beaker and rinsed properly with acetone, then isopropanol, and finally DI water to eliminate any polymers.

To deposit the thin film, a hot plate was turned on and set up to 100 ℃. Once the hot plate reached the desired temperature (100 ℃), a chip was placed on it. A 100 µL pipette was used to deposit three times 30 µL of solution, separately for GO and CNT. Each time that 30 µL of solution was added on the surface of the chip, it was allowed to dry and evaporate. These steps were repeated three times, alternating for each nanomaterial and obtaining a final nanocomposite thin film made up of a total of 90 µL of GO and 90 µL of CNT. The same procedure was repeated for each condition to which the nanoparticles were exposed (oxygen, UV, control-aged, and control-fresh). Once the nanocomposite thin films had been deposited on a chip for each condition, samples were placed in a sealed container and taken out of the cleanroom to the regular lab to conduct the experiment.

The equipment used for these experiments was prepared before resistance measurements were taken and before and after exposure to the CO₂ gas contaminant. The Printed Circuit Board (PCB) used for the purposes of these experiments consisted of two layers, 20 mm width and 50 mm length with four copper traces on opposite and alternate sides of the board. Each copper trace was approximately 6 mm wide and 18 mm long. Two spring clips were welded on alternate sides of the PCB. A Keithley 2420 source meter was turned on and adjusted to "Ohm" option (MΩ), and cables were properly connected while making sure that there was current flow before measurements started. The chamber used for the purposes of these experiments consisted of a cubic crystal box of 21 cm², 2 cm thick with eight clips for hermetic seal. On its top, there was a vacuum pump for monitoring air pressure. Inside, there were four conducting cylindrical tubes used to measure any type of electric current (e.g., resistance).

The chamber was set up by connecting the CO₂ tank to the vacuum pump for CO₂ exposure. On finalization of the equipment set-up, the electrode chip was placed on the PCB, held by the two spring clips inside the chamber. To properly place an electrode chip onto the PCB, both spring clips touched parallel electrodes on chip at all times and in a steady manner. The two PCB clips always made contact with two of the four conducing cylindrical tubes of the chamber. Finally, using the source meter, measurements of resistance were taken for each thin film. Cables (clamps preferably) were connected from the source meter to the chamber for resistance measurements, and values were recorded.

To record resistance values after exposure, the CO₂ tank was opened slightly to allow a current of CO₂ to enter the chamber. Then, after 60 seconds of acclimatization, exposure to CO₂ was allowed before the resistance on the electrode chip was measured. After time had elapsed, the resistance was again recorded. The same procedure was repeated for each condition to which the nanoparticles were exposed (oxygen, UV, control-aged, and control-fresh). The schematic diagram of the overall experimental procedure is shown in Scheme 1. Statistical significance was confirmed and determined using the Holm-Sidak method, with alpha = 0.05. Each row was analyzed individually, without assuming a consistent SD.

Results and Discussion

Physicochemical properties of the model nanomaterials under environmental exposure

As one of the physicochemical properties of the model NMs, absorbance was measured when the NMs were exposed to each environmental condition (i.e., aging, oxygenation, UV irradiation, and temperature). Since absorbance is the ability of a material to absorb light [31], the absorbance value of the material would be low when a large amount of light was capable of passing through a material. By contrast, when a small amount of light passed through the material, the absorbance value of the material would be high.

As shown in Figure 1A, statistically declining trends for oxygenation, heat, and UV exposure were observed from the NMs, except GO. GO may not undergo transformation under the environmental conditions. This result is consistent with a study [32] in which GO showed no degradation when GO was exposed to a total of 700 hours of UV-A radiation and humidity at 50 ℃, elucidating a similar absorbance value of GO after 700 hours of exposure to environmental conditions. This suggests UV radiation may not have a detrimental effect on GO. Notably, ZnO NW showed a significantly declining trend over all environmental conditions, and ZnO exhibited significant absorbance decrease under O₂ and UV-irradiation exposure over time.

The declines occurred especially at days 7 and 14 may suggest a longer transformation time for zinc-involved nanoparticles. A study involving ZnO showed that longer wavelengths of light are not absorbed well by ZnO, but shorter wavelengths are [33], with a relative peak witnessed at 377 nm and attributed to ZnO in the organic phase. The UV and oxygenated conditions seem to be crucial in improving performance of devices that incorporate ZnO. For instance, a recent study revealed improved performance of a gas sensor because of increasing viability of using ZnO as a gas sensor when either an oxygen-rich or ultraviolet (UV) radiation environmental condition was given [23].

Slight absorbance decreases over time under the environmental exposure conditions were observed from TiO₂ nanoparticles (NPs), indicating that TiO₂ NPs do not experience large changes to optical sensitivity over 14 days, 56 accumulative hours, of environmental exposure conditions. The absorbance measurement was reported to be dependent on molar absorptivity, path length, and the concentration of the absorbing chemical species [34]. In addition, absorbance measured by UV-Vis Spectroscopy highlights the concentration of a material, in addition to the absorbance measurement [35]. Results suggest at a constant concentration of the model NMs, various factors including UV irradiation, temperature, and oxygenation influence the absorbance of a material. A study by Fleger and Rosenbluh [36], investigating the absorption spectra of gold and silver NPs, elucidated the influence of concentration of the material on the absorption spectra, with peaks ranging from 450 to 500 nm.

Zeta potential values measured were also assessed as one of physicochemical properties of the model nanomaterials under the environmental exposure conditions. Figure 1B exhibits changes of the zeta potential, which describes ion adsorption and electrostatic interactions between charged particles [37]. While measuring zeta potential values may be challenging because of the complex nature of NMs under the environmental exposure conditions, the values could still be used as a metric of stability. As shown in Figure 1B, overall decrease in zeta potential values was found regardless of the type of NMs under the environmental exposure conditions over time.

Among the NMs, significant decreases in zeta potential of TiO₂ were noted under temperature, oxygenation, and UV irradiation. Semiconductor NPs such as TiO₂ that act as photocatalysts are well known to undergo a chemical transformation from UV exposure in an aqueous solution, thus producing hydroxyl radicals and forming a redox condition [38,39]. It was shown that chemical transformation increases the hydrophilicity of a nanomaterial while reducing fouling and improving water flux [39]. This phenomenon was hypothesized to cause a decline in the zeta potential of TiO₂/GO membranes that were exposed to UV radiation, which similar observation occurred in the present study. When NMs form hydroxyl groups during the hydrophilic conversion of TiO₂/GO membranes from UV activation, zeta potential was decreased [39].

Similarly, GO displayed a statistically significant decline in zeta potential from all exposure conditions. Research has shown possible reduction of GO by UV radiation in the presence of photocatalysts and reducing agents [39,40]; however, the sole effect of UV radiation without reducing agents is not well known [41]. To the best of our knowledge, there is a lack of research in the effects of temperature and oxygenation on the zeta potential of GO NPs.

Additionally, our results showed that ZnO and ZnO NW experienced a decline in zeta potential under the environmental exposure conditions. These results suggest instability (destabilization) and resultant aggregation of aged ZnO/ZnO NW and transformed ZnO/ZnO NW under oxygenation, temperature change, and UV irradiation. A recent study [42], which investigated the effect of increasing temperature on zeta potentials of NaCl and MgCl₂ electrolytes, revealed a decrease in the magnitude of zeta potentials (it becomes less negative) as temperature increases.

By contrast, another study [43] showed a more negative zeta potential value from α-Al₂O₃/aqueous solution with 10 mgL^-1 fluoride ions added when temperature increased, possibly due to fluoride ions that chemisorb onto the solution. A change in pH was measured and indicated to remain pH around 7.5 (± 5), indicating no remarkable change in pH and no influencing pH factor on each environmental exposure condition.

Particle sizes are related to stability and may affect the sensitivity and selectivity of NMs being used in chemical nanosensors. Hence, particle sizes of the model NMs were examined under the environmental exposure conditions. As shown in Figure 1C, significant particle size increase was observed from TiO₂ and ZnO NW under the exposure conditions over time, whereas a particle size increase of ZnO under oxygenation and a slight particle size increase in GO under the aged condition were observed. Particularly, particle sizes of GO remained few deviations under both oxygenation and ultraviolet conditions, although slightly increasing particle sizes of aged GO over time were found. Several studies [44-47] have shown that hydrophobic graphene sheets form irreversible aggregates through Van der Waals interactions. The oxidation of graphene to graphene oxide was reported to introduce hydroxyl and epoxide functional groups to the basal planes and carbonyl and carboxyl groups to the sheet edges, thus making GO sheets highly hydrophilic, thereby allowing dispersion in water and reducing aggregation [44-47].

Such dispersion of GO colloids is further stabilized by the highly negative charge of these colloids that causes electrostatic repulsions [44]. While GO tends to form less aggregation in water compared to graphene itself because of the hydrophilic nature of GO, the increase of particle size in the aged GO over time (Figure 1C) is likely to be attributed to the decrease in surface charge seen in the zeta potential. This in turn, would decrease the electrostatic repulsions between the GO colloids and lead to an increase in aggregation of these colloids, increasing the particle size measurements over time. Several studies have reported reduction in the particle size of GO when GO undergoes photoreduction reactions [48,49]. The photoreduction reactions significantly decrease the oxygen-containing functional groups (mostly epoxy and carbonyl groups) under UV irradiation, thereby producing defects in the basal planes of GO and forming holes and breakage of the nanosheets [48,49]. These studies are consistent with the observation in GO samples exposed to UV irradiation (Figure 1C).

In contrast to little changes in particle sizes of GO, a significant increase in particle size of the TiO₂ nanoparticles after long-term UV irradiation was observed. These results are consistent with other studies [50,51] in which UV irradiation has shown aggregation of TiO₂ particles as a consequence of surface interactions. Increased TiO₂ aggregation after UV irradiation is caused by the reduction in surface charge from dominant attractive Van der Waals forces over electrostatic repulsive forces [50,51]. Slight deviations in particle sizes of ZnO were observed especially under oxygenation. The extent to which particle size increases seems to depend on the types of NMs and the environmental exposure conditions.

Measuring particle size and zeta potential of CNTs in the aqueous phase was impossible because of significant and instant aggregation that exceeds the maximum values of which the equipment (Malvern Zetasizer) can analyze and measure particle sizes and zeta potential. As shown in Figure 2, most CNT particles are distributed within 1,000-1,500 nm at maximum, whereas under the environmental exposure conditions (temperature, aging, UV irradiation, and oxygenation), the maximum particle sizes are widely distributed: The fresh CNTs are shifted towards larger size ranges mostly exceeding 2,000 nm, indicating significant aggregation and possibly larger aggregation, especially under UV and oxygenation conditions.

Physical morphology changes were noted from the model NMs under the environmental exposure conditions, as shown in the SEM images (Figure 3). Most NMs showed significant aggregation. For instance, TiO₂ NPs, except fresh TiO₂ (control), revealed significant aggregation. Similarly, SEM images of GO NPs showed aggregates surrounding the GO surfaces under the environmental exposure conditions (aging, oxygenation, temperature, and UV irradiation), although the extent of aggregation was not significant compared to TiO₂ SEM images. One of the NMs, particularly CNTs, exhibited significant aggregates even including fresh CNTs (no aging and environmental exposure conditions). Changes in shape were also found in ZnO NW and ZnO NPs. As shown in Figure 3, fresh ZnO NW is needle-shaped, whereas the other treated samples (aging, O₂, temperature, and UV) showed a plate shape, indicating morphology change possibly due to chemical reactions under the exposure conditions. Similarly, compared to fresh ZnO (no aging and environmental exposure conditions), all treated samples (under aging, O₂, temperature, and UV irradiation exposure conditions) revealed aggregates to some extent. Notably, under oxygenation, the morphology of ZnO was changed from a round to a star shape.

Electrical resistance of GO-CNT thin films on environmental exposure conditions

As observed in our study shown in Section 3.1, the extent of changes in physicochemical properties of NMs depends on not only different environmental conditions but also the types of NMs. These findings are further detailed in terms of electrical resistance of GO-CNT thin films after exposure to the environmental conditions at a constant concentration of GO-CNT nanocomposite films. Given the excellent property of CNTs and GO (i.e., hybrid gas sensors incorporating CNTs into GO because of increasing electrical conductance of CNTs or GO) [2,16,18], the nanocomposite thin films consisting of GO-CNT were chosen and examined in terms of their electric resistance under UV irradiation, oxygenation, and aging after exposure to CO₂ to assess sensitivity to detect trace levels of gas contaminants (Figure 4).

According to several studies [52-54], a change in resistance occurs when a chemical reaction is carried out within the surface of the chip whose resistance is being measured. It was noted that such a change of resistance occurred due to the depletion or accumulation of charge carriers (CO₂) [55,56]. These results are consistent with the present study, in which oxygenated GO-CNT nanocomposite thin films showed a decrease in sensitivity after exposure to CO₂. The UV-irradiated GO-CNT nanocomposite thin films also revealed a significant change in sensitivity before and after being exposed to CO₂. These results indicate that a long-term exposure to either UV-irradiation or oxygen may cause the sensitivity (resistance) of GO-CNT nanocomposite thin films to decrease when exposed to a gas contaminant such as CO₂.

Compared to exposure to either UV irradiation or oxygen, the aged and fresh GO–CNT nanocomposite thin films showed small changes in sensitivity from exposure to CO₂, indicating that the interaction of the gas with the chip's surface does not change its sensitivity; thus, aged and fresh environmental conditions may not noticeably affect the electrical properties of the GO and CNT nanocomposite (Figure 4). Consequently, space environmental conditions may influence sensitivity and selectivity of chemical sensors in detecting gaseous contaminants, and the degree of changes may depend on physicochemical properties and types of NPs.

Conclusions

In our study, commonly used NMs in space products, including chemical sensors, were exposed to various environmental conditions to assess changes in physicochemical properties and the conditions' resultant influence on sensitivity and selectivity to detect trace levels of contaminants. Results indicated that although significant changes were noted in particle size, zeta potential, and absorbance when the selected NMs (TiO₂, ZnO, ZnO NW, CNTs, and GO) were exposed to UV irradiation and oxygenation, the degree of such changes depended on the type of NMs. For instance, the transformation of ZnO and ZnO NW was apparent, as shown in significant declining trends on absorbance, while little changes were observed in absorbance and size from GO. A significant increase in particle size for all exposure conditions from ZnO NW and TiO₂ - especially under O₂, temperature (50 ℃), and UV-irradiation exposure conditions - was observed.

A declining trend for zeta potential over time from all types of NPs was found, indicating destabilization, followed by aggregation. NPs that act as photocatalysts, e.g., TiO₂, may undergo a chemical transformation under UV exposure. As CNTs underwent aging and exposure to the environmental conditions, a wider range of size distribution occurred (beyond 2,000 nm), indicating agglomeration caused by aging and exposure conditions. Most NMs underwent significant instability with aggregation and morphology changes, especially from ZnO and ZnO NW, was observed as plate-shaped ZnO NW from a needle-shaped one and a star-shaped ZnO from a round-shaped one. A study on electrical resistance due to exposure to a gaseous contaminant suggested that CO₂-sensing ability of GO-CNT hybrid thin films is influenced by UV irradiation and oxygenation conditions; that is, after exposure to CO₂, declines in electrical resistance were noted from UV-irradiated or oxygenated GO-CNT thin films.

Nanomaterials, as routes for advancement to a wide array of conventional applications across many disciplines, are promising for gas-sensing applications, given that they can enhance early detection of gaseous contaminants because of their higher surface area and physicochemical reactivity. In space exploration, early detection of gaseous health hazards is a critical component of not only astronaut safety but also mission completion. The present study has explored how NMs are characterized in the perspective of size, electrical charge, absorbance, electrical resistance, and morphology changes when the NMs undergo transformation and/or aging processes under environmental exposure conditions. These findings, in turn, can assist in designing and developing new chemical sensors, thus better accommodating space applications.

Acknowledgments

This research was supported by the NASA through the University of Central Florida's NASA Florida Space Grant Consortium and Space Florida (Award: NNX15AI10H).

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